Effects of Substrate Structure in Neutral Hydrolysis of Crowded Sulphochlorides of Anilides of Sulphonic Acids in Organic-Water medium

Abstract

The neutral hydrolysis of sulfochlorides of anilides of sulfoacids with the screened sulphonilamid substituents was researched with the purpose of structural effects influence study in amide and sulphochloride fragments of molecule. A steric hindered sulphonic systems have actually reachable low isokinetic temperature data and the interpretation of structure factors of substituents as a mechanism criteria must consider a presence of entropy control in solvolisis reaction.